Give reactions that show the hydrohalogenation and hydration of alkynes. Write a note on the addition of hydrogen halides and water to alkynes.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Hydrohalogenation of alkynes: Alkynes undergo electrophilic addition reactions with hydrogen halides ($HCl$,$HBr$,$HI$). Two molecules of hydrogen halide add to the alkyne to form a gem-dihalide,where both halogen atoms are attached to the same carbon atom.
$(b)$ Hydration of alkynes: Hydration involves the addition of water $(H_{2}O)$ in the presence of a catalyst (e.g.,$HgSO_{4}/H_{2}SO_{4}$). The reaction proceeds via electrophilic addition. First,the electrophilic $H^{+}$ from $H_{2}O$ adds to the triple bond according to Markovnikov's rule to form a stable carbocation. Subsequently,the $OH^{-}$ ion adds to form an enol (alkenol),which then undergoes tautomerization (isomerization) to form a stable aldehyde or ketone containing the $>C=O$ group.

Explore More

Similar Questions

Acetylene gas when passed through $20\% \ H_2SO_4$ at $80 \, ^\circ C$ gives acetaldehyde. The catalyst required for this conversion is:

$CH_3-C \equiv C-O-CH_3 \xrightarrow{dil. H_2SO_4, HgSO_4} \text{major product}$

Which hydrocarbon can react with sodium in liquid ammonia?

How many structures are possible for $C_5H_8$ with one triple bond?

What is the product $A$ in the given reaction?
$C_6H_5-C \equiv C-CH_3 \xrightarrow{H^+ / Hg^{2+}} A$

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo